Pathway Details

Recommended name

Polyketide sugar unit biosynthesis

Alternative names

Reactions

D-Glucose 1-phosphate + dTTP <-> Diphosphate + dTDPglucose

dTDPglucose <-> H2O + dTDP-4-dehydro-6-deoxy-D-glucose

dTDP-4-amino-4,6-dideoxy-D-glucose + 2-Oxoglutarate <-> L-Glutamate + dTDP-4-dehydro-6-deoxy-D-glucose

dTDP-4-dehydro-6-deoxy-D-glucose <-> dTDP-4-dehydro-beta-L-rhamnose

NADP+ + dTDP-6-deoxy-L-talose <-> H+ + NADPH + dTDP-4-dehydro-beta-L-rhamnose

NADP+ + dTDP-L-rhamnose <-> H+ + NADPH + dTDP-4-dehydro-beta-L-rhamnose

dTDP-4-dehydro-6-deoxy-D-glucose <-> dTDP-3-oxo-6-deoxy-D-glucose

2 S-Adenosyl-L-methionine + dTDP-3-amino-3,4,6-trideoxy-alpha-D-glucose <-> 2 S-Adenosyl-L-homocysteine + dTDP-3-dimethylamino-3,4,6-trideoxy-D-glucose

NADP+ + dTDP-D-fucose <-> H+ + NADPH + 4,6-Dideoxy-4-oxo-dTDP-D-glucose

L-Glutamate + 3,6-Dideoxy-3-oxo-dTDP-D-glucose <-> 2-Oxoglutarate + dTDP-3-amino-3,6-dideoxy-D-glucose

4,6-Dideoxy-4-oxo-dTDP-D-glucose <-> 3,6-Dideoxy-3-oxo-dTDP-D-glucose

3,6-Dideoxy-3-oxo-dTDP-D-glucose <-> dTDP-3-oxo-4,6-dideoxy-D-glucose

L-Glutamate + dTDP-3-oxo-4,6-dideoxy-D-glucose <-> dTDP-3-amino-3,4,6-trideoxy-D-glucose + 2-Oxoglutarate

2 S-Adenosyl-L-methionine + dTDP-3-amino-3,4,6-trideoxy-D-glucose <-> 2 S-Adenosyl-L-homocysteine + dTDP-D-desosamine

4,6-Dideoxy-4-oxo-dTDP-D-glucose <-> H2O + dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran

H+ + NADPH + dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran <-> NADP+ + dTDP-4-oxo-2,6-dideoxy-D-allose

H+ + NADPH + dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran <-> NADP+ + dTDP-4-oxo-2,6-dideoxy-D-glucose

H+ + NADPH + dTDP-4-oxo-2,6-dideoxy-D-glucose <-> NADP+ + dTDP-L-olivose

S-Adenosyl-L-methionine + dTDP-L-olivose <-> H+ + S-Adenosyl-L-homocysteine + dTDP-L-oleandrose

dTDP-4-oxo-2,6-dideoxy-D-allose <-> dTDP-4-oxo-2,6-dideoxy-L-mannose

H+ + NADPH + dTDP-4-oxo-2,6-dideoxy-L-mannose <-> NADP+ + dTDP-L-olivose

S-Adenosyl-L-methionine + dTDP-4-oxo-2,6-dideoxy-L-mannose <-> H+ + S-Adenosyl-L-homocysteine + dTDP-3-methyl-4-oxo-2,6-dideoxy-L-glucose

H+ + NADPH + dTDP-3-methyl-4-oxo-2,6-dideoxy-L-glucose <-> NADP+ + dTDP-L-mycarose

4,6-Dideoxy-4-oxo-dTDP-D-glucose <-> dTDP-4-oxo-6-deoxy-D-allose

dTDP-4-oxo-6-deoxy-D-allose <-> dTDP-6-deoxy-D-allose

2 S-Adenosyl-L-methionine + dTDP-3-amino-3,6-dideoxy-D-glucose <-> 2 H+ + 2 S-Adenosyl-L-homocysteine + dTDP-D-mycaminose

dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran <-> dTDP 1-ester with (6S)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran

dTDP 1-ester with (6S)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran <-> dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose

dTDP 1-ester with 2,6-dideoxy-L-erythro-hexopyranos-3-ulose <-> dTDP-L-megosamine

dTDP 1-ester with (6R)-5,6-dihydro-4-hydroxy-6-methyl-5-oxo-2H-pyran <-> Maltol

dTDP-4-dehydro-beta-L-rhamnose <-> dTDP-4-oxo-2,6-dideoxy-L-mannose

dTDP-4-oxo-2,6-dideoxy-D-glucose <-> dTDP-D-olivose

dTDPglucose <-> H2O + 4,6-Dideoxy-4-oxo-dTDP-D-glucose

4,6-Dideoxy-4-oxo-dTDP-D-glucose <-> dTDP-4-dehydro-beta-L-rhamnose

alpha-D-Glucose 1-phosphate + dTTP <-> Diphosphate + dTDP-D-glucose

dTDP-D-glucose <-> H2O + dTDP-4-dehydro-6-deoxy-D-glucose

dTDP-D-glucose <-> H2O + 4,6-Dideoxy-4-oxo-dTDP-D-glucose

Classification

Metabolism of Terpenoids and Polyketides

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