Pathway Details

 Recommended name Biosynthesis of ansamycins
 Alternative names
 Reactions
27-O-Demethyl-rifamycin SV <-> Rifamycin
NAD+ + UDP-D-glucose <-> NADH + H+ + UDP-3-ketoglucose
Phosphoenolpyruvate + H2O + Iminoerythrose 4-phosphate <-> Phosphate + AminoDAHP
Rifamycin <-> Rifamycin S
Rifamycin W <-> Rifamycin W-hemiacetal
Rifamycin W-hemiacetal <-> Demethyl-desacetyl-rifamycin S
Rifamycin Z <-> Demethyl-desacetyl-rifamycin S
Proansamycin X <-> Rifamycin W
Protorifamycin I <-> Rifamycin W
Demethyl-desacetyl-rifamycin S <-> Demethyl-desacetyl-rifamycin SV
Proansamycin X <-> Protorifamycin I
AminoDHQ <-> H2O + AminoDHS
NAD+ + UDPglucose <-> NADH + H+ + UDP-3-ketoglucose
Rifamycin <-> Rifamycin B
Demethyl-desacetyl-rifamycin SV <-> 27-O-Demethyl-rifamycin SV
Rifamycin W <-> Rifamycin Z
ATP + Kanosamine <-> ADP + Kanosamine 6-phosphate
Rifamycin W <-> Rifamycin B
AminoDAHP <-> Phosphate + AminoDHQ
Kanosamine 6-phosphate <-> Aminofructose 6-phosphate
AminoDHS <-> H2O + AHBA
Proansamycin X <-> 34a-Deoxy-rifamycin W
UDP-3-ketoglucose <-> UDP-kanosamine
UDP-kanosamine <-> Kanosamine
34a-Deoxy-rifamycin W <-> Rifamycin W
D-Ribose 5-phosphate + Aminofructose 6-phosphate <-> D-Sedoheptulose 7-phosphate + Iminoerythrose 4-phosphate
 Classification
Metabolism of Terpenoids and Polyketides
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